Soft x-rays are used to probe the outer layers of the sample. Emitted photoeletrons are being analyzed by energy in the analyzer and plotted as a function of binding energy. Resulting spectrum is obtained from the sample layers within ~3 nm in depth thus giving great surface sensitivity.
Thin films and semiconductors
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Surface segregation
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Surface sensitive analysis
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Parallel imaging of chemical state (Si vs SiO2)
Surface Oxides and Glasses
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Layering (stratification)
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Depth information
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Polymers and Organics
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Functional groups according to the chemical shift
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Bonding information, presence of catalysts traces, etc.
Metals
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Oxidation states
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Metal oxide to metal layers
Catalysis
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Characterization of surface components on catalyst
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Characterizationof catalysis products and intermediates
Biological
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Elemental information from thin layers (sections)
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Presence of trace elements, mineral, etc.
Depth Profiling Using Focused Ion Bean
Non-destructive depth profiling using angle resolved XPS
Other applications include fast parallel elemental, Auger and secondary election imaging, Auger spectroscopy, UPS spectroscopy.