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An approximate lecture schedule is given below:
- Lecture #1
- The Atmosphere
- Introduction
- the biosphere and chemical cycling
- atmospheric structure
- pressure profile
- Lecture #2
- temperature profile
- radiative energy balance
- surface coordinates and zenith angles
- Lecture #3
- global atmospheric circulation
- chemical composition of the atmospher
- carbon, nitrogen, sulfur cycles
- review of kinetics
- Lecture #4
- solar irradiance
- photochemical rates and quantum yields
- chemistry of the thermosphere
- chemistry of the stratosphere
- the ozone layer
- Chapman mechanism
- Lecture #5
- catalytic O3 destruction cycles
- impact of chlorofluorocarbons (CFCs)
- Lecture #6
- chemistry of the troposphere
- O3 and OH formation mechanisms
- photochemical hydrocarbon oxidation
- Lecture #7
- OH chemistry
- NO3 chemistry
- photochemical smog
- effect of VOC and NOx on O3 formation
- Lecture #8
- introduction to aerosols
- liquid aerosol formation
- supersaturation
- Kelvin effect
- Lecture #9
- Henry's Law and trace gas partitioning
- Lecture #10
- CO2-water equilibrium
- acid rain phenomenon
- trace gas equilibria
- pollution and remediation strategies
- Lecture #11
- atmospheric aerosol
- sources, sizes, and chemical composition
- formation and growth mechanisms
- loss mechanisms
- Lecture #12
- heterogeneous atmospheric chemistry
- gas kinetic and diffusion limited regimes
- adsorption isotherms
- aerosols as sinks and sources for trace gases
- Lecture #13
- aerosol optical properties
- light scattering
- Rayleigh scattering
- Mie scattering
- geometric optics
- extinction by background/volcanic aerosols
- Lecture #14
- global climate
- radiative energy balance
- greenhouse gas effect
- radiative forcing and climate sensitivity
- historical trends
- Lecture #15
- aerosol forcing
- future climate change
- The Hydropshere
- global water reservoirs
- Lecture #16
- Lecture #17
- ocean and lake structure and composition
- properties of water
- seasonal overturn
- acid-base properties
- Lecture #18
- speciation diagrams
- effects of ionic strength
- estuary
- Lecture #19
- two-dimensional stability diagrams
- electron activity
- redox and acid/base properties of natural waters
- pe-pH diagram for metals and sulfur species
- Lecture #20
- gas-water interactions
- CO2(g) equilibrium with CaCO3(s)
- ocean pH
- climatic effects and feedback
- Lecture #21
- buffer effects
- alkalinity
- buffer capacity of natural waters
- organic material in the hydrosphere
- DOC and humic material
- characteristics of humic material
- composition and structure
- chemical interactions of humic material
- Lecture #22
- photochemistry in surface waters
- chromophoric species
- pathways and lifetimes
- metals in the hydrosphere
- complex formation and chelation effects
- speciation
- Lecture #23
- dissolution and deposition processes
- silica solubility
- chemical weathering
- global geochemical cycles
- Lecture #24
- colloids and surface chemistry
- colloid characterization
- surface functional groups
- surface charge
- Lecture #25
- colloid stability
- effects of ionic strength and pH
- surface properties at high ionic strength
- adsorption onto colloids
- Langmuir and alternative isotherms
- Lecture #26
- octanol-water partition coefficients
- clay colloids
- structure
- cation exchange capacity
- colloid photochemistry
- Lecture #27
- biotic processes
- microorganism classification
- biotic processes in the carbon-cycle
- biotic processes in the nitrogen-cycle
- fixation, ammonification, nitrification, denitrification
- Lecture #28
- Lecture #29
- The Lithosphere
- composition and structure of the lithosphere
- weathering processes
- clays
- Lecture #30
- organic matter in soil
- classification of organic matter
- composition and formation
- physical properties of soil
- chemical properties of soil
- Final Project Due
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